Palladium-Catalyzed Borylation of Aryl Mesylates and Tosylates and Their Applications in One-Pot Sequential Suzuki-Miyaura Biaryl Synthesis

Palladium-Catalyzed Borylation of Aryl Mesylates and Tosylates and Their Applications in One-Pot Sequential Suzuki-Miyaura Biaryl Synthesis

Top of the one‐pots! The first palladium‐catalyzed borylation of aryl tosylates and mesylates is described. The reaction conditions are mild and provide excellent functional‐group compatibility (e.g., R=CN, CHO, COOMe, C(O)R, NH2, or NH‐indole; see scheme). Pd/MeO‐CM‐phos allows one‐pot sequential r...

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Veröffentlicht in:Chemistry : a European journal 2011-06, Vol.17 (25), p.6913-6917
Hauptverfasser: Chow, Wing Kin, So, Chau Ming, Lau, Chak Po, Kwong, Fuk Yee
Format: Artikel
Sprache:eng
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Aromatic compounds
biaryls
borylation
Chemistry
Compatibility
cross-coupling
Palladium
phosphine
Synthesis
tosylates
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container_issue 25
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container_title Chemistry : a European journal
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creator Chow, Wing Kin
So, Chau Ming
Lau, Chak Po
Kwong, Fuk Yee
description Top of the one‐pots! The first palladium‐catalyzed borylation of aryl tosylates and mesylates is described. The reaction conditions are mild and provide excellent functional‐group compatibility (e.g., R=CN, CHO, COOMe, C(O)R, NH2, or NH‐indole; see scheme). Pd/MeO‐CM‐phos allows one‐pot sequential reactions in the preparation of unsymmetrical biaryls.
doi_str_mv 10.1002/chem.201100361
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source Wiley Online Library Journals Frontfile Complete
subjects Aromatic compounds
biaryls
borylation
Chemistry
Compatibility
cross-coupling
Palladium
phosphine
Synthesis
tosylates
title Palladium-Catalyzed Borylation of Aryl Mesylates and Tosylates and Their Applications in One-Pot Sequential Suzuki-Miyaura Biaryl Synthesis
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