Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride-triazolophane complexes

Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride-triazolophane complexes

Structural rigidity is verified as a pre-organizational factor that acts together with the macrocyclic effect such that synthesis helps in paying the cost of bringing together electropositive CH donors ready for H-bonding with chloride.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-06, Vol.47 (21), p.5979-5981
Hauptverfasser: Hua, Yuran, Ramabhadran, Raghunath O, Karty, Jonathan A, Raghavachari, Krishnan, Flood, Amar H
Format: Artikel
Sprache:eng
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Zusammenfassung:Structural rigidity is verified as a pre-organizational factor that acts together with the macrocyclic effect such that synthesis helps in paying the cost of bringing together electropositive CH donors ready for H-bonding with chloride.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc10428d