A new coordination tetra-mer of copper(I) iodide and benzyl-dimethyl-amine: tetra-μ(3)-iodido-tetra-kis[(benzyl-dimethyl-amine-κN)copper(I)]
The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distan...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-07, Vol.65 (Pt 8), p.m906-m906 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) Å. |
|---|---|
| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536809026208 |