Amine-Tethered Solid Adsorbents Coupling High Adsorption Capacity and Regenerability for CO2 Capture From Ambient Air

Silica supported poly(ethyleneimine) (PEI) materials are prepared via impregnation and demonstrated to be promising adsorbents for CO2 capture from ultra‐dilute gas streams such as ambient air. A prototypical class 1 adsorbent, containing 45 wt % PEI (PEI/silica), and two new modified PEI‐based aminosilica adsorbents, derived from PEI modified with 3‐aminopropyltrimethoxysilane (A‐PEI/silica) or tetraethyl orthotitanate (T‐PEI/silica), are prepared and characterized by using thermogravimetric analysis and FTIR spectroscopy. The modifiers are shown to enhance the thermal stability of the polymer‐oxide composites, leading to higher PEI decomposition temperatures. The modified adsorbents present extremely high CO2 adsorption capacities under conditions simulating ambient air (400 ppm CO2 in inert gas), exceeding 2 mol CO 2 kgsorbent−1, as well as enhanced adsorption kinetics compared to conventional class 1 sorbents. The new adsorbents show excellent stability in cyclic adsorption–desorption operations, even under dry conditions in which aminosilica adsorbents are known to lose capacity due to urea formation. Thus, the adsorbents of this type can be considered promising materials for the direct capture of CO2 from ultra‐dilute gas streams such as ambient air. Solid amine adsorbents targeting ultra‐dilute CO2, such as ambient air, are demonstrated to present extremely high capacity and outstanding regenerability. Prototypical PEI‐based, class 1 adsorbents, are modified by additives to yield enhanced thermal stability in the polymer‐oxide composites. The modified aminosilica materials realize adsorption capacities exceeding 2 mol CO 2 kgsorbent−1 from simulated air (400 ppm CO2) and offer excellent stability in cyclic adsorption–desorption operation.