Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

Hydrolysis of a Pacman-shaped binuclear magnesium complex of a polypyrrolic Schiff base macrocycle results in the formation of a new magnesium hydroxide cubane that is encapsulated by the macrocyclic framework through both coordinative and hydrogen-bonding interactions.

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Veröffentlicht in:Journal of the American Chemical Society 2011-05, Vol.133 (19), p.7320-7323
Hauptverfasser: Leeland, James W, White, Fraser J, Love, Jason B
Format: Artikel
Sprache:eng
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Zusammenfassung:Hydrolysis of a Pacman-shaped binuclear magnesium complex of a polypyrrolic Schiff base macrocycle results in the formation of a new magnesium hydroxide cubane that is encapsulated by the macrocyclic framework through both coordinative and hydrogen-bonding interactions.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja201630b