Helix-Sense-Selective Polymerization of Achiral Substituted Acetylenes in Chiral Micelles

Helix-Sense-Selective Polymerization of Achiral Substituted Acetylenes in Chiral Micelles

Hold that shape: An achiral acetylene underwent helix‐sense‐selective polymerization in chiral micelles consisting of [{(nbd)RhCl}2] (nbd=2,5‐norbornadiene) and dodecylphenylalanine as a chiral emulsifier to produce optically active helical polymers and polymeric emulsions.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2011-05, Vol.50 (21), p.4909-4912
Hauptverfasser: Luo, Xiaofeng, Deng, Jianping, Yang, Wantai
Format: Artikel
Sprache:eng
Schlagworte:
chirality
helical structures
micelles
polymerization
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Hold that shape: An achiral acetylene underwent helix‐sense‐selective polymerization in chiral micelles consisting of [{(nbd)RhCl}2] (nbd=2,5‐norbornadiene) and dodecylphenylalanine as a chiral emulsifier to produce optically active helical polymers and polymeric emulsions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201006658