1,1′-Azobis(tetrazole): A Highly Energetic Nitrogen-Rich Compound with a N10 Chain

1,1′-Azobis(tetrazole): A Highly Energetic Nitrogen-Rich Compound with a N10 Chain

The reaction of 1-aminotetrazole with acidic sodium dichloroisocyanurate allowed isolation of 1,1′-azobis(tetrazole). The rare chain of 10 nitrogen atoms in this compound was confirmed by X-ray crystallography, and the physical and explosive properties of the azo compound were characterized. The tit...

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Veröffentlicht in:Inorganic chemistry 2011-04, Vol.50 (7), p.2732-2734
Hauptverfasser: Klapötke, Thomas M, Piercey, Davin G
Format: Artikel
Sprache:eng
Schlagworte:
Azo Compounds - chemical synthesis
Azo Compounds - chemistry
Crystallography, X-Ray
Models, Molecular
Molecular Structure
Tetrazoles - chemical synthesis
Tetrazoles - chemistry
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Zusammenfassung:The reaction of 1-aminotetrazole with acidic sodium dichloroisocyanurate allowed isolation of 1,1′-azobis(tetrazole). The rare chain of 10 nitrogen atoms in this compound was confirmed by X-ray crystallography, and the physical and explosive properties of the azo compound were characterized. The title compound possesses both exceedingly high explosive performance and sensitivity.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic200071q