Dynamics of Relaxation and Fluctuations of the Equilibrium State in an Incompletely Chaotic System
An incompletely chaotic system, with a perturbation of the integrable part that does not obey selection rules, relaxes to an equilibrium state that lies between the initial state and thermal equilibrium. We analyze here a system of two atoms in a circular transversally harmonic waveguide. The dynami...
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Veröffentlicht in: | The journal of physical chemistry. B 2011-05, Vol.115 (18), p.5340-5346 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | An incompletely chaotic system, with a perturbation of the integrable part that does not obey selection rules, relaxes to an equilibrium state that lies between the initial state and thermal equilibrium. We analyze here a system of two atoms in a circular transversally harmonic waveguide. The dynamics of expectation values of generic observables and their fluctuations in the long-time limit are studied for this model. The relaxation demonstrates a nonexponential behavior and slows down as the initial-state energy increases. The fluctuation amplitude has a tendency to decrease with an increase of the initial state width. |
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ISSN: | 1520-6106 1520-5207 |
DOI: | 10.1021/jp109388x |