Exclusive enantioselective recognition of glucopyranosides by inherently chiral hemicryptophanes

Exclusive enantioselective recognition of glucopyranosides by inherently chiral hemicryptophanes

Inherently chiral hemicryptophanes were used to complex β- and α-glucoside derivatives with high diastereo- and enantio-selectivity. In most cases, the exclusive recognition by the M-hemicryptophane enantiomers was observed.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (20), p.5861-5863
Hauptverfasser: Perraud, Olivier, Martinez, Alexandre, Dutasta, Jean-Pierre
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Derivatives
Enantiomers
Glucosides - chemistry
or physical chemistry
Polycyclic Compounds - chemistry
Recognition
Stereoisomerism
Theoretical and
Thermodynamics
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Beschreibung
Zusammenfassung:Inherently chiral hemicryptophanes were used to complex β- and α-glucoside derivatives with high diastereo- and enantio-selectivity. In most cases, the exclusive recognition by the M-hemicryptophane enantiomers was observed.
ISSN:1359-7345
0022-4936
1364-548X
DOI:10.1039/c1cc10964b