Ruthenium-Catalyzed One-Pot Aromatic Secondary Amine Formation from Nitroarenes and Alcohols

Ruthenium-Catalyzed One-Pot Aromatic Secondary Amine Formation from Nitroarenes and Alcohols

Beg, steal, or borrow: The synthesis of aromatic secondary amines has been developed using commercially available [Ru(acac)3]/dppe as the catalyst. Chlorobenzene solvent gave high selectivity, with only trace amounts of imine and tertiary amine observed.

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Bibliographische Detailangaben
Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2011-05, Vol.6 (5), p.1142-1146
Hauptverfasser: Liu, Yong, Chen, Wen, Feng, Chao, Deng, Guojun
Format: Artikel
Sprache:eng
Schlagworte:
alcohols
Alcohols - chemistry
alkylation
Amines - chemical synthesis
Amines - chemistry
Catalysis
Chemistry
Coordination Complexes - chemistry
nitroarenes
Nitrobenzenes - chemistry
Oxidation-Reduction
ruthenium
Ruthenium - chemistry
secondary amines
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Beschreibung
Zusammenfassung:Beg, steal, or borrow: The synthesis of aromatic secondary amines has been developed using commercially available [Ru(acac)3]/dppe as the catalyst. Chlorobenzene solvent gave high selectivity, with only trace amounts of imine and tertiary amine observed.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201000945