Precise Assembly of Photo-functional Molecules in Phenylazomethine Dendrimer

Precise Assembly of Photo-functional Molecules in Phenylazomethine Dendrimer

Precise assembly of photo-functional molecules on dendritic phenylazomethine (DPA) was demonstrated. We previously reported the precise assembly of metal ions on dendritic phenylazomethine in stepwise radical fashion. Triphenylmethylium tetrafluoroborate (TPMBF4) could be coordinated to the imine gr...

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Veröffentlicht in:Journal of Photopolymer Science and Technology 2009/06/30, Vol.22(4), pp.513-514
Hauptverfasser: Ochi, Yousuke, Miyagawa, Yuji, Yamamoto, Kimihisa
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
azobenzene
Dendrimers
Dendritic Polyphenylazomethine
Derivatives
Imines
Metal ions
Photopolymers
Radicals
Stepwise radial complexation
Trityl cation
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Zusammenfassung:Precise assembly of photo-functional molecules on dendritic phenylazomethine (DPA) was demonstrated. We previously reported the precise assembly of metal ions on dendritic phenylazomethine in stepwise radical fashion. Triphenylmethylium tetrafluoroborate (TPMBF4) could be coordinated to the imine group of DPA, which allows for control of the number and position of organic molecules in DPA. As one of the applications of an organic molecular assembly, TPM+ derivatives holding a photo-functional molecule, azobenzene (Azo-TPM), were incorporated into DPA stepwisely.
ISSN:0914-9244
1349-6336
1349-6336
DOI:10.2494/photopolymer.22.513