C2N14: An Energetic and Highly Sensitive Binary Azidotetrazole

7:1 to nitrogen! Diazotization and subsequent dimerization of the triaminoguanidinium cation gave 1‐diazidocarbamoyl‐5‐azidotetrazole (see picture). The structurally and spectroscopically characterized binary CN compound shows great energetic performance and a high heat of formation, but also extrem...

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Veröffentlicht in:	Angewandte Chemie International Edition 2011-04, Vol.50 (18), p.4227-4229
Hauptverfasser:	Klapötke, Thomas M., Martin, Franz A., Stierstorfer, Jörg
Format:	Artikel
Sprache:	eng
Schlagworte:	azides binary CN compounds energetic materials heterocycles nitrogen
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	7:1 to nitrogen! Diazotization and subsequent dimerization of the triaminoguanidinium cation gave 1‐diazidocarbamoyl‐5‐azidotetrazole (see picture). The structurally and spectroscopically characterized binary CN compound shows great energetic performance and a high heat of formation, but also extremely high sensitivity to friction and shock.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201100300