Competitive formation of cis and trans derivatives in the nucleophilic substitution reactions of cyclophosphazenes having a mono-spiro P-NHR group

Nucleophilic substitution reactions of N(3)P(3)Cl(4)[NH(CH(2))(3)NMe] (1) and N(3)P(3)Cl(4)[NH(CH(2))(3)O] (2) with mono-functional alcohols (methanol, 2,2,2-trifluoroethanol, phenol) and a secondary amine (pyrrolidine) were used to investigate the relationship between the incoming nucleophile and t...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2011-05, Vol.40 (18), p.4959-4969
Hauptverfasser: Beşli, Serap, Coles, Simon J, Davies, David B, Kılıç, Adem, Okutan, Elif, Shaw, Robert A, Eçik, Esra Tanrıverdi, Çiftçi, Gönül Yenilmez
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Sprache:eng
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