Competitive formation of cis and trans derivatives in the nucleophilic substitution reactions of cyclophosphazenes having a mono-spiro P-NHR group
Nucleophilic substitution reactions of N(3)P(3)Cl(4)[NH(CH(2))(3)NMe] (1) and N(3)P(3)Cl(4)[NH(CH(2))(3)O] (2) with mono-functional alcohols (methanol, 2,2,2-trifluoroethanol, phenol) and a secondary amine (pyrrolidine) were used to investigate the relationship between the incoming nucleophile and t...
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Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2011-05, Vol.40 (18), p.4959-4969 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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