1,4-Hydrosilylation of Pyridine by Ruthenium Catalyst: A New Reaction and Mechanism

1,4-Hydrosilylation of Pyridine by Ruthenium Catalyst: A New Reaction and Mechanism

Making introductions: A half‐sandwich Ru complex catalyzes the hydrosilylation of pyridine derivatives to produce N‐silyl‐3‐hydropyridine through a 1,4‐addition of the Si–H group (see scheme). The reversibility of the hydrosilylation was suggested based on the experimental results.

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Veröffentlicht in:Angewandte Chemie International Edition 2011-04, Vol.50 (17), p.3845-3846
1. Verfasser: Osakada, Kohtaro
Format: Artikel
Sprache:eng
Schlagworte:
homogeneous catalysis
hydrosilylation
pyridine
Ruthenium
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Zusammenfassung:Making introductions: A half‐sandwich Ru complex catalyzes the hydrosilylation of pyridine derivatives to produce N‐silyl‐3‐hydropyridine through a 1,4‐addition of the Si–H group (see scheme). The reversibility of the hydrosilylation was suggested based on the experimental results.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201008199