Regiocontrolled Rearrangement of Isobenzofurans

Regiocontrolled Rearrangement of Isobenzofurans

The regioselective alkylation and oxidative rearrangement of isobenzofurans has been achieved to generate substituted 4,8-dihydroxyisochromanones in good yields and with complete regiocontrol.

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Veröffentlicht in:Organic letters 2011-04, Vol.13 (8), p.2086-2089
Hauptverfasser: Egan, Ben A, Paradowski, Michael, Thomas, Lynne H, Marquez, Rodolfo
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Benzofurans - chemistry
Models, Molecular
Molecular Structure
Oxidation-Reduction
Stereoisomerism
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Beschreibung
Zusammenfassung:The regioselective alkylation and oxidative rearrangement of isobenzofurans has been achieved to generate substituted 4,8-dihydroxyisochromanones in good yields and with complete regiocontrol.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol200498k