Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry

Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry

Catching a glimpse: Electrospray ionization mass spectrometry (ESI‐MS) allows monitoring of the real‐time, “in‐solution” formation of an organic–inorganic polyoxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese‐Anderson...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-04, Vol.50 (16), p.3720-3724
Hauptverfasser: Wilson, Elizabeth F., Miras, Haralampos N., Rosnes, Mali H., Cronin, Leroy
Format: Artikel
Sprache:eng
Schlagworte:
manganese
mass spectrometry
polyoxometalates
self-assembly
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Zusammenfassung:Catching a glimpse: Electrospray ionization mass spectrometry (ESI‐MS) allows monitoring of the real‐time, “in‐solution” formation of an organic–inorganic polyoxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese‐Anderson cluster coordinated with tris(hydroxymethyl)aminomethane ligands, through the rearrangement of the [α‐Mo8O26]4− cluster in the presence of Mn(CH3CO2)3.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201006938