An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals

An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals

A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1′-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.

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Veröffentlicht in:Journal of the American Chemical Society 2011-04, Vol.133 (13), p.4680-4683
Hauptverfasser: Williams, Bryan N, Benitez, Diego, Miller, Kevin L, Tkatchouk, Ekaterina, Goddard, William A, Diaconescu, Paula L
Format: Artikel
Sprache:eng
Schlagworte:
Hydrogen - chemistry
Models, Molecular
Molecular Conformation
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Pyridines - chemistry
Quantum Theory
Stereoisomerism
Yttrium - chemistry
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Zusammenfassung:A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1′-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja110505r