Synthesis of N-Confused Porphyrin Derivatives with a Substituted 3-C Position

Active methylene compounds such as 5,5-dimethylcyclohexane-1,3-dione, cyclohexane-1,3-dione, 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one, 1,3-dimethyl-1H-pyrazol-5(4H)-one, and 3-methylisoxazol-5(4H)-one react with the 3-C position of N-confused porphyrin in THF for 5 min to afford a novel type of N-conf...

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Veröffentlicht in:	Journal of organic chemistry 2011-04, Vol.76 (7), p.2345-2349
Hauptverfasser:	Li, Xiaofang, Liu, Bin, Yi, Pinggui, Yi, Rongqiong, Yu, Xianyong, Chmielewski, Piotr J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Crystallography, X-Ray Cyclohexanes - chemistry Cyclohexanones - chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Molecular Structure Organic chemistry Porphyrins - chemical synthesis Porphyrins - chemistry Preparations and properties Pyrazoles - chemistry
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Beschreibung
Zusammenfassung:	Active methylene compounds such as 5,5-dimethylcyclohexane-1,3-dione, cyclohexane-1,3-dione, 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one, 1,3-dimethyl-1H-pyrazol-5(4H)-one, and 3-methylisoxazol-5(4H)-one react with the 3-C position of N-confused porphyrin in THF for 5 min to afford a novel type of N-confused porphyrin derivatives in good yield without the need of any catalyst.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo200040x