Access to an unusual Fe9 core topology from the initial use of tricine in iron(III) cluster chemistry

Access to an unusual Fe9 core topology from the initial use of tricine in iron(III) cluster chemistry

We describe an enneanuclear Fe(III) complex with an unusual boat-shaped core topology and an S=11/2 ground state, assembled using the ligands tricine {N-(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)glycine, H(4)L} and 2-phenoxybenzoate.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2011-04, Vol.40 (13), p.3125-3127
Hauptverfasser: Graham, Kristoffer, Ferguson, Alan, Douglas, Fraser J, Thomas, Lynne H, Murrie, Mark
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Coordination Complexes - chemistry
Glycine - analogs & derivatives
Glycine - chemistry
Ground state
Iron - chemistry
Ligands
Molecular Conformation
Prints
Temperature
Topology
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Zusammenfassung:We describe an enneanuclear Fe(III) complex with an unusual boat-shaped core topology and an S=11/2 ground state, assembled using the ligands tricine {N-(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)glycine, H(4)L} and 2-phenoxybenzoate.
ISSN:1477-9226
1477-9234
DOI:10.1039/c0dt01712d