Hexagonal wheel formation through the hydrogen-bonded assembly of cobalt Pacman complexes

Hexagonal wheel formation through the hydrogen-bonded assembly of cobalt Pacman complexes

A cobalt aquo-hydroxo complex of a ditopic Schiff-base pyrrole-crown ether macrocycle has been prepared and forms a rigid Pacman-clefted structure that assembles through hydrogen-bonding into a hexagonal wheel motif in the solid state.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (14), p.4132-4134
Hauptverfasser: Leeland, James W, White, Fraser J, Love, Jason B
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Cobalt
Ethers
Solid state
Wheels
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Beschreibung
Zusammenfassung:A cobalt aquo-hydroxo complex of a ditopic Schiff-base pyrrole-crown ether macrocycle has been prepared and forms a rigid Pacman-clefted structure that assembles through hydrogen-bonding into a hexagonal wheel motif in the solid state.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc04883f