Nature-inspired cascade catalysis: reaction control through substrate concentration--double vs. quadruple domino reactions

The design of biologically inspired, multi-component cascade reactions enables the targeted synthesis of assorted structurally complex products. Similar to regulation in cells the reaction path is controlled by the substrate concentration and complex enantiopure products with high structural diversi...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (13), p.3828-3830
Hauptverfasser:	Rueping, Magnus, Haack, KyoungLang, Ieawsuwan, Winai, Sundén, Henrik, Blanco, Magda, Schoepke, Fenja R
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemical synthesis Biomimetics - methods Cascade chemical reactions Cascade control Cascades Catalysis Control Reaction control Stereoisomerism Synthesis
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The design of biologically inspired, multi-component cascade reactions enables the targeted synthesis of assorted structurally complex products. Similar to regulation in cells the reaction path is controlled by the substrate concentration and complex enantiopure products with high structural diversity are provided.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c1cc10245a