Interplay of geomorphic and hydrogeologic features at reach- and channel unit-scales on riverbed hydrology and hydrochemistry: a conceptual model in the Lower Coal Measures, South Yorkshire, UK

A conceptual model of groundwater and surface-water interactions in areas of minor aquifers has been developed. It assesses the interplay of reach-scale subsurface flow paths (RSSF), controlled by the lateral extent of the alluvial valley, and channel unit-scale hyporheic flow paths (CUSHF), controlled by riffle and run/pool sequences, and their impacts on the spatial variability of riverbed flow and solute exchange. A network of riverbed mini-piezometers and multi-level samplers in different reach- and channel-unit scale settings of the River Don (South Yorkshire, UK) is monitored to: (1) estimate vertical hydraulic gradients (VHGs) and specific discharge; (2) discriminate subsurface flow paths from conservative natural tracers; and (3) deduce biogeochemical processes. In a constrained context (downstream end of the alluvial valley), RSSF discharge favours a homogeneous riverbed hydrochemistry with limited biogeochemical processes and shallow CUSHF. In an unconstrained (open alluvial valley) or asymmetric (bedrock outcropping on one bank) context, low VHGs favour deep CUSHF and a vertical stratification of RSSF. Reducing conditions intensify with depth, and superimpose with mixing in riffles. This good approximation of flow and solute behaviour in minor aquifers provides a practical framework to understand nutrient and contaminant fate and develop cost-effective monitoring programmes across the groundwater/surface-water interface.