An engineered anisotropic nanofilm with unidirectional wetting properties

Anisotropic textured surfaces allow water striders to walk on water, butterflies to shed water from their wings and plants to trap insects and pollen. Capturing these natural features in biomimetic surfaces is an active area of research. Here, we report an engineered nanofilm, composed of an array of poly( p -xylylene) nanorods, which demonstrates anisotropic wetting behaviour by means of a pin-release droplet ratchet mechanism. Droplet retention forces in the pin and release directions differ by up to 80 μN, which is over ten times greater than the values reported for other engineered anisotropic surfaces. The nanofilm provides a microscale smooth surface on which to transport microlitre droplets, and is also relatively easy to synthesize by a bottom-up vapour-phase technique. An accompanying comprehensive model successfully describes the film’s anisotropic wetting behaviour as a function of measurable film morphology parameters. Hydrophobic surfaces composed of an asymmetric array of polymer nanorods show unidirectional wetting behaviour relative to the orientation of the tilted nanorods. The surfaces, which are smooth on the microscale, can transport water droplets of microlitre capacity by a ratcheting mechanism resulting from the pillared substrate.