Oxide ionic conductivity and crystallographic properties of tetragonal type Bi sub(2)O sub(3)-based solid electrolyte doped with Ho sub(2)O sub(3)

In the present work, the authors have investigated the binary system of (Bi sub(2)O sub(3)) sub(1-x)(Ho sub(2)O sub(3)) sub(x). For the stabilisation of the tetragonal type solid solution, small amounts of Ho sub(2)O sub(3) were doped into the monoclinic Bi sub(2)O sub(3) via solid state reactions in the stoichiometric range 0.01 less than or equal to x less than or equal to 0.1. The crystal formula of the formed solid solution was determined as Bi(III) sub(4-4x)Ho(II) sub(4x)O sub(6)-2xo sub((2+2x)) (where Vo is the oxide ion vacancy) according to the XRD and SEM microprobe results. In the crystal formula, stoichiometric values of x were 0.04 less than or equal to x less than or equal to 0.08, 0.03 less than or equal to x less than or equal to 0.09, 0.02 less than or equal to x less than or equal to 0.09 and 0.04 less than or equal to x less than or equal to 0.09 for annealing temperatures at 750, 800, 805 (quench) and 760 degree C (quench) respectively. The four probe electrical conductivity measurements showed that the studied system had an oxide ionic type electrical conductivity behaviour, which is increased with increasing dopant concentration and temperature. The obtained solid electrolyte system has an oxygen non-stoichiometry characteristic, and it contains O super(2-) vacancies, which have disordered arrangements in its tetragonal crystal structure. The increase in the amount of Ho sub(2)O sub(3) doping and temperature causes an increasing degree of the disordering of oxygen vacancies and a decrease in the activation energy E sub(a).