Autoxidative Annulation Cascade of the α-Cyano β-TMS-capped Alkynyl Cycloalkanone System
The autoxidative annulation cascade promoted by an α-cyano β-TMS-capped alkynyl cycloalkanone system under catalysis with pyridine in one oxygen atmosphere has proven to be highly viable. On the basis of this newly developed protocol, a variety of highly functionalized bicyclic frameworks can be eff...
Gespeichert in:
Veröffentlicht in: | Organic letters 2011-03, Vol.13 (5), p.896-899 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 899 |
---|---|
container_issue | 5 |
container_start_page | 896 |
container_title | Organic letters |
container_volume | 13 |
creator | Wong, Ying-Chieh Hsieh, Min-Tsang Amancha, Prashanth K Chin, Chih-Lung Liao, Cheng-Feng Kuo, Chun-Wei Shia, Kak-Shan |
description | The autoxidative annulation cascade promoted by an α-cyano β-TMS-capped alkynyl cycloalkanone system under catalysis with pyridine in one oxygen atmosphere has proven to be highly viable. On the basis of this newly developed protocol, a variety of highly functionalized bicyclic frameworks can be effectively constructed. |
doi_str_mv | 10.1021/ol102947u |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_853996381</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>853996381</sourcerecordid><originalsourceid>FETCH-LOGICAL-a314t-a8df5706e226e3a8239fe84f691dc7c09b805b2fb7eac6c00f2b4d42cf56be713</originalsourceid><addsrcrecordid>eNptkMtOwzAURC0EoqWw4AeQNwixCPiRl5dVxEsqYtGyYRM5zrVI68QhThD5LPiQfhOpWrpiNaOro9HcQeickhtKGL21ZhDhR90BGtOAcS8iATvc-5CM0IlzS0LocBHHaMQoJyJgZIzepl1rv4pctsUn4GlVdWawtsKJdErmgK3G7Tvg9beX9LKyeP3jLZ7nnpJ1DTmemlVf9QYnvTJWmtVAVIDnvWuhPEVHWhoHZzudoNf7u0Xy6M1eHp6S6cyTnPqtJ-NcB0NJYCwELmPGhYbY16GguYoUEVlMgozpLAKpQkWIZpmf-0zpIMwgonyCrra5dWM_OnBtWhZOgTGyAtu5NA64ECGPN-T1llSNda4BndZNUcqmTylJN0um-yUH9mKX2mUl5Hvyb7oBuNwCUrl0abumGp78J-gXSkR79A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>853996381</pqid></control><display><type>article</type><title>Autoxidative Annulation Cascade of the α-Cyano β-TMS-capped Alkynyl Cycloalkanone System</title><source>ACS Publications</source><source>MEDLINE</source><creator>Wong, Ying-Chieh ; Hsieh, Min-Tsang ; Amancha, Prashanth K ; Chin, Chih-Lung ; Liao, Cheng-Feng ; Kuo, Chun-Wei ; Shia, Kak-Shan</creator><creatorcontrib>Wong, Ying-Chieh ; Hsieh, Min-Tsang ; Amancha, Prashanth K ; Chin, Chih-Lung ; Liao, Cheng-Feng ; Kuo, Chun-Wei ; Shia, Kak-Shan</creatorcontrib><description>The autoxidative annulation cascade promoted by an α-cyano β-TMS-capped alkynyl cycloalkanone system under catalysis with pyridine in one oxygen atmosphere has proven to be highly viable. On the basis of this newly developed protocol, a variety of highly functionalized bicyclic frameworks can be effectively constructed.</description><identifier>ISSN: 1523-7060</identifier><identifier>EISSN: 1523-7052</identifier><identifier>DOI: 10.1021/ol102947u</identifier><identifier>PMID: 21309520</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Alkynes - chemistry ; Combinatorial Chemistry Techniques ; Ketones - chemical synthesis ; Ketones - chemistry ; Molecular Structure ; Nitriles - chemical synthesis ; Nitriles - chemistry ; Pyridines - chemistry ; Stereoisomerism ; Trimethylsilyl Compounds - chemical synthesis ; Trimethylsilyl Compounds - chemistry</subject><ispartof>Organic letters, 2011-03, Vol.13 (5), p.896-899</ispartof><rights>Copyright © 2011 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a314t-a8df5706e226e3a8239fe84f691dc7c09b805b2fb7eac6c00f2b4d42cf56be713</citedby><cites>FETCH-LOGICAL-a314t-a8df5706e226e3a8239fe84f691dc7c09b805b2fb7eac6c00f2b4d42cf56be713</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ol102947u$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ol102947u$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21309520$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wong, Ying-Chieh</creatorcontrib><creatorcontrib>Hsieh, Min-Tsang</creatorcontrib><creatorcontrib>Amancha, Prashanth K</creatorcontrib><creatorcontrib>Chin, Chih-Lung</creatorcontrib><creatorcontrib>Liao, Cheng-Feng</creatorcontrib><creatorcontrib>Kuo, Chun-Wei</creatorcontrib><creatorcontrib>Shia, Kak-Shan</creatorcontrib><title>Autoxidative Annulation Cascade of the α-Cyano β-TMS-capped Alkynyl Cycloalkanone System</title><title>Organic letters</title><addtitle>Org. Lett</addtitle><description>The autoxidative annulation cascade promoted by an α-cyano β-TMS-capped alkynyl cycloalkanone system under catalysis with pyridine in one oxygen atmosphere has proven to be highly viable. On the basis of this newly developed protocol, a variety of highly functionalized bicyclic frameworks can be effectively constructed.</description><subject>Alkynes - chemistry</subject><subject>Combinatorial Chemistry Techniques</subject><subject>Ketones - chemical synthesis</subject><subject>Ketones - chemistry</subject><subject>Molecular Structure</subject><subject>Nitriles - chemical synthesis</subject><subject>Nitriles - chemistry</subject><subject>Pyridines - chemistry</subject><subject>Stereoisomerism</subject><subject>Trimethylsilyl Compounds - chemical synthesis</subject><subject>Trimethylsilyl Compounds - chemistry</subject><issn>1523-7060</issn><issn>1523-7052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkMtOwzAURC0EoqWw4AeQNwixCPiRl5dVxEsqYtGyYRM5zrVI68QhThD5LPiQfhOpWrpiNaOro9HcQeickhtKGL21ZhDhR90BGtOAcS8iATvc-5CM0IlzS0LocBHHaMQoJyJgZIzepl1rv4pctsUn4GlVdWawtsKJdErmgK3G7Tvg9beX9LKyeP3jLZ7nnpJ1DTmemlVf9QYnvTJWmtVAVIDnvWuhPEVHWhoHZzudoNf7u0Xy6M1eHp6S6cyTnPqtJ-NcB0NJYCwELmPGhYbY16GguYoUEVlMgozpLAKpQkWIZpmf-0zpIMwgonyCrra5dWM_OnBtWhZOgTGyAtu5NA64ECGPN-T1llSNda4BndZNUcqmTylJN0um-yUH9mKX2mUl5Hvyb7oBuNwCUrl0abumGp78J-gXSkR79A</recordid><startdate>20110304</startdate><enddate>20110304</enddate><creator>Wong, Ying-Chieh</creator><creator>Hsieh, Min-Tsang</creator><creator>Amancha, Prashanth K</creator><creator>Chin, Chih-Lung</creator><creator>Liao, Cheng-Feng</creator><creator>Kuo, Chun-Wei</creator><creator>Shia, Kak-Shan</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20110304</creationdate><title>Autoxidative Annulation Cascade of the α-Cyano β-TMS-capped Alkynyl Cycloalkanone System</title><author>Wong, Ying-Chieh ; Hsieh, Min-Tsang ; Amancha, Prashanth K ; Chin, Chih-Lung ; Liao, Cheng-Feng ; Kuo, Chun-Wei ; Shia, Kak-Shan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a314t-a8df5706e226e3a8239fe84f691dc7c09b805b2fb7eac6c00f2b4d42cf56be713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alkynes - chemistry</topic><topic>Combinatorial Chemistry Techniques</topic><topic>Ketones - chemical synthesis</topic><topic>Ketones - chemistry</topic><topic>Molecular Structure</topic><topic>Nitriles - chemical synthesis</topic><topic>Nitriles - chemistry</topic><topic>Pyridines - chemistry</topic><topic>Stereoisomerism</topic><topic>Trimethylsilyl Compounds - chemical synthesis</topic><topic>Trimethylsilyl Compounds - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wong, Ying-Chieh</creatorcontrib><creatorcontrib>Hsieh, Min-Tsang</creatorcontrib><creatorcontrib>Amancha, Prashanth K</creatorcontrib><creatorcontrib>Chin, Chih-Lung</creatorcontrib><creatorcontrib>Liao, Cheng-Feng</creatorcontrib><creatorcontrib>Kuo, Chun-Wei</creatorcontrib><creatorcontrib>Shia, Kak-Shan</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Organic letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wong, Ying-Chieh</au><au>Hsieh, Min-Tsang</au><au>Amancha, Prashanth K</au><au>Chin, Chih-Lung</au><au>Liao, Cheng-Feng</au><au>Kuo, Chun-Wei</au><au>Shia, Kak-Shan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Autoxidative Annulation Cascade of the α-Cyano β-TMS-capped Alkynyl Cycloalkanone System</atitle><jtitle>Organic letters</jtitle><addtitle>Org. Lett</addtitle><date>2011-03-04</date><risdate>2011</risdate><volume>13</volume><issue>5</issue><spage>896</spage><epage>899</epage><pages>896-899</pages><issn>1523-7060</issn><eissn>1523-7052</eissn><abstract>The autoxidative annulation cascade promoted by an α-cyano β-TMS-capped alkynyl cycloalkanone system under catalysis with pyridine in one oxygen atmosphere has proven to be highly viable. On the basis of this newly developed protocol, a variety of highly functionalized bicyclic frameworks can be effectively constructed.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>21309520</pmid><doi>10.1021/ol102947u</doi><tpages>4</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1523-7060 |
ispartof | Organic letters, 2011-03, Vol.13 (5), p.896-899 |
issn | 1523-7060 1523-7052 |
language | eng |
recordid | cdi_proquest_miscellaneous_853996381 |
source | ACS Publications; MEDLINE |
subjects | Alkynes - chemistry Combinatorial Chemistry Techniques Ketones - chemical synthesis Ketones - chemistry Molecular Structure Nitriles - chemical synthesis Nitriles - chemistry Pyridines - chemistry Stereoisomerism Trimethylsilyl Compounds - chemical synthesis Trimethylsilyl Compounds - chemistry |
title | Autoxidative Annulation Cascade of the α-Cyano β-TMS-capped Alkynyl Cycloalkanone System |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T19%3A26%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Autoxidative%20Annulation%20Cascade%20of%20the%20%CE%B1-Cyano%20%CE%B2-TMS-capped%20Alkynyl%20Cycloalkanone%20System&rft.jtitle=Organic%20letters&rft.au=Wong,%20Ying-Chieh&rft.date=2011-03-04&rft.volume=13&rft.issue=5&rft.spage=896&rft.epage=899&rft.pages=896-899&rft.issn=1523-7060&rft.eissn=1523-7052&rft_id=info:doi/10.1021/ol102947u&rft_dat=%3Cproquest_cross%3E853996381%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=853996381&rft_id=info:pmid/21309520&rfr_iscdi=true |