Singly N-Confused [26]Hexaphyrin: A Binucleating Porphyrinoid Ligand for Mixed Metals in Different Oxidation States

Singly N-Confused [26]Hexaphyrin: A Binucleating Porphyrinoid Ligand for Mixed Metals in Different Oxidation States

Mix and match: The title porphyrinoid has been synthesized and shows unique coordination chemistry by incorporating two different metals with different oxidation states (see figure). X‐ray crystallography was used to confirm that a rectangular conformation in both mono‐ and binuclear complexes was r...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2011-03, Vol.50 (10), p.2302-2306
Hauptverfasser: Gokulnath, Sabapathi, Yamaguchi, Keisuke, Toganoh, Motoki, Mori, Shigeki, Uno, Hidemitsu, Furuta, Hiroyuki
Format: Artikel
Sprache:eng
Schlagworte:
aromaticity
conformation
Coordination Complexes - chemistry
Crystallography, X-Ray
Electrochemical Techniques
gold
Ligands
Metals - chemistry
Molecular Conformation
Oxidation-Reduction
platinum
porphyrinoids
Porphyrins - chemistry
Quantum Theory
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Beschreibung
Zusammenfassung:Mix and match: The title porphyrinoid has been synthesized and shows unique coordination chemistry by incorporating two different metals with different oxidation states (see figure). X‐ray crystallography was used to confirm that a rectangular conformation in both mono‐ and binuclear complexes was retained.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201006784