Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

A mild mannered reaction: An ideal addition of “inert” aryl CH bonds to CN groups has been achieved in the absence of any additives and without any undesirable by‐products (see scheme). The reaction can be carried out under mild conditions without the requirement of special techniques. Cp*=pentame...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2011-02, Vol.50 (9), p.2115-2119
Hauptverfasser:	Li, Yang, Li, Bi-Jie, Wang, Wen-Hua, Huang, Wei-Ping, Zhang, Xi-Sha, Chen, Kang, Shi, Zhang-Jie
Format:	Artikel
Sprache:	eng
Schlagworte:	addition reactions catalysis CH activation rhodium sulfonyl aldimines
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Beschreibung
Zusammenfassung:	A mild mannered reaction: An ideal addition of “inert” aryl CH bonds to CN groups has been achieved in the absence of any additives and without any undesirable by‐products (see scheme). The reaction can be carried out under mild conditions without the requirement of special techniques. Cp*=pentamethylcyclopentadienyl.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201007464