Aqueous Only Route toward Graphene from Graphite Oxide

We report a new, simple, hydrazine-free, high-yield method for producing single-layer graphene sheets. Graphene sheets were formed from graphite oxide by reduction with simple deionized water at 95 °C under atmospheric pressure. Over 65% of the sheets are single graphene layers; the average sheet diameter is 300 nm. We speculate that dehydration of graphene oxide is the main mechanism for oxygen reduction and transformation of C−C bonds from sp3 to sp2. The reduction appears to occur in large uniform interconnected oxygen-free patches so that despite the presence of residual oxygen the sp2 carbon bonds formed on the sheets are sufficient to provide electronic properties comparable to reduced graphene sheets obtained using other methods.