Suzuki Coupling Reactions in Three-Phase Microemulsions

The reaction medium in the Suzuki coupling shown is a three‐phase surfactant system. This medium offers advantages over conventional solvents in the reaction conversion and also in catalyst recovery. The reuse of the catalyst substantially increases the overall turnover number of the catalyst, a des...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2011-02, Vol.50 (8), p.1918-1921
Hauptverfasser: Nowothnick, Henriette, Blum, Jochanan, Schomäcker, Reinhard
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container_end_page 1921
container_issue 8
container_start_page 1918
container_title Angewandte Chemie (International ed.)
container_volume 50
creator Nowothnick, Henriette
Blum, Jochanan
Schomäcker, Reinhard
description The reaction medium in the Suzuki coupling shown is a three‐phase surfactant system. This medium offers advantages over conventional solvents in the reaction conversion and also in catalyst recovery. The reuse of the catalyst substantially increases the overall turnover number of the catalyst, a desirable factor in cost‐effective industrial applications. TPPTS=3,3′,3′′‐phosphanetriyltris(benzenesulfonic acid) trisodium salt.
doi_str_mv 10.1002/anie.201005263
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subjects Catalysis
catalyst recovery
cross-coupling
Emulsions - chemistry
homogeneous catalysis
microemulsions
Organophosphorus Compounds - chemistry
phase behavior
Sulfonic Acids - chemistry
Surface-Active Agents - chemistry
title Suzuki Coupling Reactions in Three-Phase Microemulsions
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