Suzuki Coupling Reactions in Three-Phase Microemulsions

Suzuki Coupling Reactions in Three-Phase Microemulsions

The reaction medium in the Suzuki coupling shown is a three‐phase surfactant system. This medium offers advantages over conventional solvents in the reaction conversion and also in catalyst recovery. The reuse of the catalyst substantially increases the overall turnover number of the catalyst, a des...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2011-02, Vol.50 (8), p.1918-1921
Hauptverfasser: Nowothnick, Henriette, Blum, Jochanan, Schomäcker, Reinhard
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
catalyst recovery
cross-coupling
Emulsions - chemistry
homogeneous catalysis
microemulsions
Organophosphorus Compounds - chemistry
phase behavior
Sulfonic Acids - chemistry
Surface-Active Agents - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The reaction medium in the Suzuki coupling shown is a three‐phase surfactant system. This medium offers advantages over conventional solvents in the reaction conversion and also in catalyst recovery. The reuse of the catalyst substantially increases the overall turnover number of the catalyst, a desirable factor in cost‐effective industrial applications. TPPTS=3,3′,3′′‐phosphanetriyltris(benzenesulfonic acid) trisodium salt.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201005263