Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

The catalytic dehydrocoupling reaction of Me(2)NHBH(3) with Al(NMe(2))(3) gives the dimer [Me(2)NBH(2)](2) and the chain [(Me(2)N)(2)BH], involving the thermally-stable Al(III) hydride catalyst [{(Me(2)N)(2)BH(2)}(2)AlH].

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-03, Vol.47 (9), p.2682-2684
Hauptverfasser: Cowley, Hugh J, Holt, Mark S, Melen, Rebecca L, Rawson, Jeremy M, Wright, Dominic S
Format: Artikel
Sprache:eng
Schlagworte:
Ammonia - chemistry
Boranes - chemistry
Catalysis
Catalysts
Chain reactions
Chains
Dimerization
Dimers
Hydrides
Molecular Conformation
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Zusammenfassung:The catalytic dehydrocoupling reaction of Me(2)NHBH(3) with Al(NMe(2))(3) gives the dimer [Me(2)NBH(2)](2) and the chain [(Me(2)N)(2)BH], involving the thermally-stable Al(III) hydride catalyst [{(Me(2)N)(2)BH(2)}(2)AlH].
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc05294a