Rod-like carbon nanostructures produced by the direct pyrolysis of a-cyclodextrin

Carbon nanostructures were produced by the direct pyrolysis of a cyclic glucose oligosaccharide (a-cyclodextrin) without the use of a metal catalyst. The nanorods evolve from surfaces of structureless carbon when the precursor is carbonized at 1000 C. The conversion of initially-obtained featureless...

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Veröffentlicht in:Carbon (New York) 2011-02, Vol.49 (2), p.718-722
Hauptverfasser: St Dennis, JE, Venkataraman, Pradeep, He, Jibao, John, Vijay T, Obrey, Stephen J, Currier, Robert P, Lebron-Colon, Marisabel, Sola, Francisco J, Meador, Michael A
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Sprache:eng
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Zusammenfassung:Carbon nanostructures were produced by the direct pyrolysis of a cyclic glucose oligosaccharide (a-cyclodextrin) without the use of a metal catalyst. The nanorods evolve from surfaces of structureless carbon when the precursor is carbonized at 1000 C. The conversion of initially-obtained featureless carbon to the nanostructures can be controlled by the pyrolysis time. The nanorods are of diameters 14-40 nm and consist of multiple disordered curved graphite layers with relatively short persistence lengths.
ISSN:0008-6223
DOI:10.1016/j.carbon.2010.09.027