Synthesis and structural characterization of a new yttrium phosphate: Na sub(2.5)Y sub(0.5)Mg sub(7)(PO sub(4)) sub(6) with fillowite-type structure

Synthesis and structural characterization of a new yttrium phosphate: Na sub(2.5)Y sub(0.5)Mg sub(7)(PO sub(4)) sub(6) with fillowite-type structure

A new phosphate, Na sub(2.5)Y sub(0.5)Mg sub(7)(PO sub(4)) sub(6) was synthesized as single crystals by the flux method and as a powdered sample by the Pechini technique, and investigated by single crystal X-ray diffraction, charge distribution (CD) and super(31)P NMR spectroscopy. This compound cry...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of rare earths 2010-08, Vol.28 (4), p.481-487
Hauptverfasser: Jerbi, Hasna, Hidouri, Mourad, Amara, Mongi Ben
Format: Artikel
Sprache:eng
Schlagworte:
Crystallization
Diffraction
Flux
NMR spectroscopy
Rare earth metals
Single crystals
X-rays
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A new phosphate, Na sub(2.5)Y sub(0.5)Mg sub(7)(PO sub(4)) sub(6) was synthesized as single crystals by the flux method and as a powdered sample by the Pechini technique, and investigated by single crystal X-ray diffraction, charge distribution (CD) and super(31)P NMR spectroscopy. This compound crystallized in the rhombohedral space group R [inline image]
ISSN:1002-0721
DOI:10.1016/S1002-0721(09)60137-X