Salicylbisimine Cage Compound with High Surface Area and Selective CO₂/CH₄ Adsorption

Salicylbisimine Cage Compound with High Surface Area and Selective CO₂/CH₄ Adsorption

Preference for polar adsorbates: The crystalline porous organic cage compound shown has an exceptional high surface area (1566 m2 g−1) and selective gas uptake. The compound preferably adsorbs CO2 (9.4 wt %) over methane (0.98 wt %).

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2011-02, Vol.50 (5), p.1046-1051
Hauptverfasser: Mastalerz, Michael, Schneider, Markus W, Oppel, Iris M, Presly, Oliver
Format: Artikel
Sprache:eng
Schlagworte:
adsorption
cage compounds
Carbon dioxide
gas storage
microporous materials
Schiff bases
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Zusammenfassung:Preference for polar adsorbates: The crystalline porous organic cage compound shown has an exceptional high surface area (1566 m2 g−1) and selective gas uptake. The compound preferably adsorbs CO2 (9.4 wt %) over methane (0.98 wt %).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201005301