First metal complexes of 6,6'-dihydroxy-2,2'-bipyridine: from molecular wires to applications in carbonylation catalysis

The first square planar rhodium(I) complexes containing the 6,6'-dihydroxy-2,2'-bipyridine ligand have been prepared. The complexes form molecular wires in the solid state and are active catalysts for the carbonylation of methyl acetate.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2011-01, Vol.40 (5), p.1031-1033
Hauptverfasser: Conifer, Christopher M, Taylor, Russell A, Law, David J, Sunley, Glenn J, White, Andrew J P, Britovsek, George J P
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container_issue 5
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Conifer, Christopher M
Taylor, Russell A
Law, David J
Sunley, Glenn J
White, Andrew J P
Britovsek, George J P
description The first square planar rhodium(I) complexes containing the 6,6'-dihydroxy-2,2'-bipyridine ligand have been prepared. The complexes form molecular wires in the solid state and are active catalysts for the carbonylation of methyl acetate.
doi_str_mv 10.1039/c0dt01526a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acetates
Carbonyls
Catalysis
Catalysts
Ligands
Prints
Solid state
Wire
title First metal complexes of 6,6'-dihydroxy-2,2'-bipyridine: from molecular wires to applications in carbonylation catalysis
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