First metal complexes of 6,6'-dihydroxy-2,2'-bipyridine: from molecular wires to applications in carbonylation catalysis

First metal complexes of 6,6'-dihydroxy-2,2'-bipyridine: from molecular wires to applications in carbonylation catalysis

The first square planar rhodium(I) complexes containing the 6,6'-dihydroxy-2,2'-bipyridine ligand have been prepared. The complexes form molecular wires in the solid state and are active catalysts for the carbonylation of methyl acetate.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2011-01, Vol.40 (5), p.1031-1033
Hauptverfasser: Conifer, Christopher M, Taylor, Russell A, Law, David J, Sunley, Glenn J, White, Andrew J P, Britovsek, George J P
Format: Artikel
Sprache:eng
Schlagworte:
Acetates
Carbonyls
Catalysis
Catalysts
Ligands
Prints
Solid state
Wire
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Zusammenfassung:The first square planar rhodium(I) complexes containing the 6,6'-dihydroxy-2,2'-bipyridine ligand have been prepared. The complexes form molecular wires in the solid state and are active catalysts for the carbonylation of methyl acetate.
ISSN:1477-9226
1477-9234
DOI:10.1039/c0dt01526a