Reaction of N-Halosulfonamide. I. Reaction of N, N-Dihalobenzenesulfonamide with Cyclohexene. (1)

Reaction of N-Halosulfonamide. I. Reaction of N, N-Dihalobenzenesulfonamide with Cyclohexene. (1)

Reaction between N, N-dihalobenzenesulfonamide (I) and cyclohexene (II) was studied. Addition products, DL-cis-and DL-trans-2-halo-1-benzenesulfonamidocyclohexanes (III and IV), and by-products, DL-trans-1, 2-dihalocyclohexane (V), 1, 3-cyclohexadiene (VI), 1-cyclohexen-3-one (VIII) and benzenesulfo...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1967/08/25, Vol.15(8), pp.1193-1197
Hauptverfasser: Ueno, Yoshio, Takemura, Shoji, Ando, Yoshiko, Terauchi, Hiromi
Format: Artikel
Sprache:eng
Schlagworte:
Benzene Derivatives
Chemical Phenomena
Chemistry
Cyclohexanes
Halogens
Sulfonamides
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Zusammenfassung:Reaction between N, N-dihalobenzenesulfonamide (I) and cyclohexene (II) was studied. Addition products, DL-cis-and DL-trans-2-halo-1-benzenesulfonamidocyclohexanes (III and IV), and by-products, DL-trans-1, 2-dihalocyclohexane (V), 1, 3-cyclohexadiene (VI), 1-cyclohexen-3-one (VIII) and benzenesulfonamide (VII) were isolated and identified from the reaction mixture. A presumption on this reaction was also drawn.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.15.1193