On-Off Porosity Switching in a Molecular Organic Solid

Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2011-01, Vol.50 (3), p.749-753
Hauptverfasser:	Jones, James T.A, Holden, Daniel, Mitra, Tamoghna, Hasell, Tom, Adams, Dave J, Jelfs, Kim E, Trewin, Abbie, Willock, David J, Day, Graeme M, Bacsa, John, Steiner, Alexander, Cooper, Andrew I
Format:	Artikel
Sprache:	eng
Schlagworte:	conformers cooperative diffusion Crystallization microporous materials molecular cages Molecular Dynamics Simulation Organic Chemicals - chemistry Porosity
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Pulling the old switcheroo: Microporosity can be switched “on” and “off” in a crystalline molecular organic solid composed of cage molecules (see scheme). The switch is facilitated by conformational flexibility in the soft organic crystal state.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201006030