Oxidation of steroidal ketones—IV : Reinvestigation of selenium dioxide-hydrogen peroxide oxidation of ring a saturated 3-ketones
Oxidation of steroidal 3-ketones in the 5α and 5β series leads to ring A contracted acids and to products of bond scission on either side of the carbonyl. No directional influence by the ring A/B junction on the course of reaction previously indicated 3 was detected. The published results 3 are appr...
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Veröffentlicht in: | Tetrahedron 1964-05, Vol.20 (5), p.1271-1277 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Oxidation of steroidal 3-ketones in the 5α and 5β series leads to ring A contracted acids and to products of bond scission on either side of the carbonyl. No directional influence by the ring A/B junction on the course of reaction previously indicated
3
was detected. The published results
3
are appropriately amended. |
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ISSN: | 0040-4020 1464-5416 |
DOI: | 10.1016/S0040-4020(01)98991-4 |