Synthesis of Vitamin A via Sulfones: A C15 Sulfone Route

Synthesis of Vitamin A via Sulfones: A C15 Sulfone Route

A Synthesis of vitamin A has been achieved by alkylating a β‐ionylidene‐ethyl (C15) aromatic sulfone with 1‐acetoxy‐3‐chlormethyl‐2‐butene (C5) followed by elimination of the corresponding sulfinic acid.

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Bibliographische Detailangaben
Veröffentlicht in:Helvetica chimica acta 1976-03, Vol.59 (2), p.387-396
Hauptverfasser: Manchand, P. S., Rosenberger, M., Saucy, G., Wehrli, P. A., Wong, H., Chambers, L., Ferro, M. P., Jackson, W.
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Methods
Sulfones
Vitamin A - chemical synthesis
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Beschreibung
Zusammenfassung:A Synthesis of vitamin A has been achieved by alkylating a β‐ionylidene‐ethyl (C15) aromatic sulfone with 1‐acetoxy‐3‐chlormethyl‐2‐butene (C5) followed by elimination of the corresponding sulfinic acid.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19760590207