Guests on Different Internal Capsule Sites Exchange with Each Other and with the Outside

Guests on Different Internal Capsule Sites Exchange with Each Other and with the Outside

In and out: Compartmentalization in a porous polyoxometalate capsule (see structure, red and blue polyhedra) allows acetate ions (green/red or orange/red), coordinated to different internal sites, to exchange not only with each other (yellow double arrow) but also with those outside in bulk aqueous...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2011-01, Vol.50 (2), p.410-414
Hauptverfasser: Petina, Olga, Rehder, Dieter, Haupt, Erhard T.K, Grego, Alina, Weinstock, Ira A, Merca, Alice, Bögge, Hartmut, Szakács, Julia, Müller, Achim
Format: Artikel
Sprache:eng
Schlagworte:
capsules
equilibria
guest exchange
NMR spectroscopy
polyoxometalates
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Beschreibung
Zusammenfassung:In and out: Compartmentalization in a porous polyoxometalate capsule (see structure, red and blue polyhedra) allows acetate ions (green/red or orange/red), coordinated to different internal sites, to exchange not only with each other (yellow double arrow) but also with those outside in bulk aqueous solution.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201005596