Sulfur-containing Pyridine Derivatives. XLVII. Behavior of 3-Nitro-4-thiocyanopyridine to Aliphatic Alcohols.(2)

Sulfur-containing Pyridine Derivatives. XLVII. Behavior of 3-Nitro-4-thiocyanopyridine to Aliphatic Alcohols.(2)

1) The application of Kitamura's reaction to ethyl 3-nitropyridyl-4-thiocarbamate resulted in the formation of ethyl 3-nitropyridyl-4-carbamate, which was identical with the product obtained by the reaction of 3-nitro-4-aminopyridine with ClCO2C2H5. 2) The reaction mechanism of the thiocyano co...

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Veröffentlicht in:Pharmaceutical Bulletin 1956/04/20, Vol.4(2), pp.133-135
Hauptverfasser: Takahashi, Torizo, Ueda, Kan-ichi
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Old Medline
Pyridines
Sulfur
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Zusammenfassung:1) The application of Kitamura's reaction to ethyl 3-nitropyridyl-4-thiocarbamate resulted in the formation of ethyl 3-nitropyridyl-4-carbamate, which was identical with the product obtained by the reaction of 3-nitro-4-aminopyridine with ClCO2C2H5. 2) The reaction mechanism of the thiocyano compound with alcohols was reconsidered.
ISSN:0369-9471
1881-1345
DOI:10.1248/cpb1953.4.133