Definite coordination arrangement of organometallic palladium complexes accumulated on the designed interior surface of apo-ferritin

Definite coordination arrangement of organometallic palladium complexes accumulated on the designed interior surface of apo-ferritin

Apo-ferritin (apo-Fr) mutants are used as scaffolds to accommodate palladium (allyl) complexes. Various coordination arrangements of the Pd complexes are achieved by adjusting the positions of cysteine and histidine residues on the interior surface of the apo-Fr cage.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (1), p.170-172
Hauptverfasser: Wang, Ziyue, Takezawa, Yusuke, Aoyagi, Hiroki, Abe, Satoshi, Hikage, Tatsuo, Watanabe, Yoshihito, Kitagawa, Susumu, Ueno, Takafumi
Format: Artikel
Sprache:eng
Schlagworte:
Animals
Apoferritins - chemistry
Apoferritins - genetics
Apoferritins - metabolism
Crystallography, X-Ray
Horses
Models, Molecular
Mutation
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Organometallic Compounds - metabolism
Palladium - chemistry
Surface Properties
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Zusammenfassung:Apo-ferritin (apo-Fr) mutants are used as scaffolds to accommodate palladium (allyl) complexes. Various coordination arrangements of the Pd complexes are achieved by adjusting the positions of cysteine and histidine residues on the interior surface of the apo-Fr cage.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc02221g