Metal-Mediated Oxidative Cross-Coupling of Terminal Alkynes: A Promising Strategy for Alkyne Synthesis

Metal-Mediated Oxidative Cross-Coupling of Terminal Alkynes: A Promising Strategy for Alkyne Synthesis

Oxidative heterocoupling of terminal alkynes mediated by metal complexes has emerged as a promising new strategy for the incorporation of alkynyl functionality into organic molecules (see scheme). Recent key developments in the construction of CspC sp 3, CspC sp 2, CspCsp, and Cspheteroatom bond...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-12, Vol.49 (50), p.9566-9568
Hauptverfasser: Shao, Zhihui, Peng, Fangzhi
Format: Artikel
Sprache:eng
Schlagworte:
alkynes
Alkynes - chemical synthesis
Alkynes - chemistry
Catalysis
cross-coupling
homogeneous catalysis
Metals - chemical synthesis
Metals - chemistry
oxidation
Oxidation-Reduction
synthetic methods
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Zusammenfassung:Oxidative heterocoupling of terminal alkynes mediated by metal complexes has emerged as a promising new strategy for the incorporation of alkynyl functionality into organic molecules (see scheme). Recent key developments in the construction of CspC sp 3, CspC sp 2, CspCsp, and Cspheteroatom bonds are highlighted.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201003081