Versatile Method for the Synthesis of 4-Aminocyclopentenones: Dysprosium(III) Triflate Catalyzed Aza-Piancatelli Rearrangement
A sweet dysprosition: A dysprosium(III) trifluoromethanesulfonate catalyzed rearrangement of furylcarbinols into 4‐aminocyclopentenones by a 4π electrocyclization has been developed. The aza‐Piancatelli rearrangement affords a single trans diastereomer from both aryl‐ and alkyl‐substituted furylcarb...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-12, Vol.49 (49), p.9484-9487 |
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| container_issue | 49 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Veits, Gesine K Wenz, Donald R Read de Alaniz, Javier |
| description | A sweet dysprosition: A dysprosium(III) trifluoromethanesulfonate catalyzed rearrangement of furylcarbinols into 4‐aminocyclopentenones by a 4π electrocyclization has been developed. The aza‐Piancatelli rearrangement affords a single trans diastereomer from both aryl‐ and alkyl‐substituted furylcarbinols. |
| doi_str_mv | 10.1002/anie.201005131 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-12, Vol.49 (49), p.9484-9487 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Catalysis cyclization Cyclopentanes - chemical synthesis Cyclopentanes - chemistry domino reactions dysprosium Dysprosium - chemistry Furans - chemistry lanthanides Mesylates - chemistry Molecular Structure rearrangement Stereoisomerism |
| title | Versatile Method for the Synthesis of 4-Aminocyclopentenones: Dysprosium(III) Triflate Catalyzed Aza-Piancatelli Rearrangement |
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