A STUDY OF THE STRUCTURE OF BLUENSOMYCIN WITH THE TETRAMMINECOPPER REAGENT
A polarimetric study was made of the interaction of the tetramminecopper (TACu) reagent and the Cupra B reagent with bluensomycin, desamidinodecarbamoyl (DADC) bluensomycin, and several reference compounds of the streptomycin series. The results obtained with TACu support the choice of 5b as the cor...
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| Veröffentlicht in: | Journal of antibiotics 1972/05/25, Vol.25(5), pp.281-286 |
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| container_end_page | 286 |
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| container_issue | 5 |
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| container_title | Journal of antibiotics |
| container_volume | 25 |
| creator | BARLOW, G. B. ANDERSON, LAURENS |
| description | A polarimetric study was made of the interaction of the tetramminecopper (TACu) reagent and the Cupra B reagent with bluensomycin, desamidinodecarbamoyl (DADC) bluensomycin, and several reference compounds of the streptomycin series. The results obtained with TACu support the choice of 5b as the correct formula for DADC-bluensomycin. It follows that bluensomycin is 9, and bluensidine is 1D-1-O-carbamoyl-3-deoxy-3-guanidino-scyllo-inositol (2). A phosphorylated aminosugar, D-glucosamine 1-phosphate, gives a normal Δ[M] value with TACu. |
| doi_str_mv | 10.7164/antibiotics.25.281 |
| format | Article |
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B. ; ANDERSON, LAURENS</creator><creatorcontrib>BARLOW, G. B. ; ANDERSON, LAURENS</creatorcontrib><description>A polarimetric study was made of the interaction of the tetramminecopper (TACu) reagent and the Cupra B reagent with bluensomycin, desamidinodecarbamoyl (DADC) bluensomycin, and several reference compounds of the streptomycin series. The results obtained with TACu support the choice of 5b as the correct formula for DADC-bluensomycin. It follows that bluensomycin is 9, and bluensidine is 1D-1-O-carbamoyl-3-deoxy-3-guanidino-scyllo-inositol (2). 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B.</creatorcontrib><creatorcontrib>ANDERSON, LAURENS</creatorcontrib><title>A STUDY OF THE STRUCTURE OF BLUENSOMYCIN WITH THE TETRAMMINECOPPER REAGENT</title><title>Journal of antibiotics</title><addtitle>J. Antibiot.</addtitle><description>A polarimetric study was made of the interaction of the tetramminecopper (TACu) reagent and the Cupra B reagent with bluensomycin, desamidinodecarbamoyl (DADC) bluensomycin, and several reference compounds of the streptomycin series. The results obtained with TACu support the choice of 5b as the correct formula for DADC-bluensomycin. It follows that bluensomycin is 9, and bluensidine is 1D-1-O-carbamoyl-3-deoxy-3-guanidino-scyllo-inositol (2). A phosphorylated aminosugar, D-glucosamine 1-phosphate, gives a normal Δ[M] value with TACu.</description><subject>Anti-Bacterial Agents</subject><subject>Chemical Phenomena</subject><subject>Chemistry</subject><subject>Copper</subject><subject>Dihydrostreptomycin Sulfate</subject><subject>Glucosamine</subject><subject>Glucosephosphates</subject><subject>Indicators and Reagents</subject><subject>Models, Chemical</subject><subject>Optical Rotation</subject><issn>0021-8820</issn><issn>1881-1469</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1972</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpNkEtPwzAQhC0EgvL4A0hIOXFL8cZ2vD2WYGihDxQSIU6WGzsQ1AfE6YF_T0qrisuudmfmOwwhl0C7EmJ-Y5ZNNatWTVX4biS6EcIB6QAihMDj3iHpUBpBiBjRE3Lq_SelTDKJx-SYA3DOoUMe-8FLlt-9BdP7IBuo9kjzJMtTtXncjnI1eZmO35LhJHgdZoM_S6aytD8eDycqmT4_qzRIVf9BTbJzclSauXcXu31G8nuVJYNwNH0YJv1RWHAZNyGztBdbJ_jMMGvQiZLTUqBDFA5AFgJxhqKUljkU0gonTFHIuMdtbKyLLTsj11vuV736Xjvf6EXlCzefm6Vbrb1GECAZZa0x2hqLeuV97Ur9VVcLU_9ooHpToP5XoI6EbgtsQ1c7-nq2cHYf2TXW6k9b_dM35t3tdVO3lLn7j4RejBus2A2Evav4MLV2S_YLztqETw</recordid><startdate>19720101</startdate><enddate>19720101</enddate><creator>BARLOW, G. B.</creator><creator>ANDERSON, LAURENS</creator><general>JAPAN ANTIBIOTICS RESEARCH ASSOCIATION</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19720101</creationdate><title>A STUDY OF THE STRUCTURE OF BLUENSOMYCIN WITH THE TETRAMMINECOPPER REAGENT</title><author>BARLOW, G. B. ; ANDERSON, LAURENS</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c476t-3d096de54ba3da8e5f40f58e885e117c588b85f7d3e857d5e5acc7694d6ade6d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1972</creationdate><topic>Anti-Bacterial Agents</topic><topic>Chemical Phenomena</topic><topic>Chemistry</topic><topic>Copper</topic><topic>Dihydrostreptomycin Sulfate</topic><topic>Glucosamine</topic><topic>Glucosephosphates</topic><topic>Indicators and Reagents</topic><topic>Models, Chemical</topic><topic>Optical Rotation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>BARLOW, G. B.</creatorcontrib><creatorcontrib>ANDERSON, LAURENS</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of antibiotics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>BARLOW, G. B.</au><au>ANDERSON, LAURENS</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A STUDY OF THE STRUCTURE OF BLUENSOMYCIN WITH THE TETRAMMINECOPPER REAGENT</atitle><jtitle>Journal of antibiotics</jtitle><addtitle>J. Antibiot.</addtitle><date>1972-01-01</date><risdate>1972</risdate><volume>25</volume><issue>5</issue><spage>281</spage><epage>286</epage><pages>281-286</pages><issn>0021-8820</issn><eissn>1881-1469</eissn><abstract>A polarimetric study was made of the interaction of the tetramminecopper (TACu) reagent and the Cupra B reagent with bluensomycin, desamidinodecarbamoyl (DADC) bluensomycin, and several reference compounds of the streptomycin series. The results obtained with TACu support the choice of 5b as the correct formula for DADC-bluensomycin. It follows that bluensomycin is 9, and bluensidine is 1D-1-O-carbamoyl-3-deoxy-3-guanidino-scyllo-inositol (2). A phosphorylated aminosugar, D-glucosamine 1-phosphate, gives a normal Δ[M] value with TACu.</abstract><cop>Japan</cop><pub>JAPAN ANTIBIOTICS RESEARCH ASSOCIATION</pub><pmid>4114441</pmid><doi>10.7164/antibiotics.25.281</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | The Journal of Antibiotics, 1972/05/25, Vol.25(5), pp.281-286 |
| issn | 0021-8820 1881-1469 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_81517303 |
| source | MEDLINE; J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese |
| subjects | Anti-Bacterial Agents Chemical Phenomena Chemistry Copper Dihydrostreptomycin Sulfate Glucosamine Glucosephosphates Indicators and Reagents Models, Chemical Optical Rotation |
| title | A STUDY OF THE STRUCTURE OF BLUENSOMYCIN WITH THE TETRAMMINECOPPER REAGENT |
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