Application of trans and cis isomers of p-nitrophenyl-(1 R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate to the assay of pyrethroid-hydrolyzing esterases
A continuous-rate assay for the detection of esterases which hydrolyze synthetic pyrethroids is described. The assay is based on the release of p-nitrophenolate ion upon hydrolysis of the pyrethroid-like compound, trans- or cis-p-nitrophenyl-(1 R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarb...
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| Veröffentlicht in: | Analytical biochemistry 1983-07, Vol.132 (1), p.105-109 |
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| container_title | Analytical biochemistry |
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| creator | Riddles, Peter W. Schnitzerling, Herbert J. Davey, Patricia A. |
| description | A continuous-rate assay for the detection of esterases which hydrolyze synthetic pyrethroids is described. The assay is based on the release of
p-nitrophenolate ion upon hydrolysis of the pyrethroid-like compound,
trans- or
cis-p-nitrophenyl-(1
R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, at pH 7.4 where spontaneous hydrolysis is not detected. The reagent is solubilized by 0.02% Triton X-100 in the presence of 1.0% ethanol. A simple procedure for the synthesis and separation of the isomers is described. The application of the reagent to the assay of esterases which detoxify synthetic pyrethroids in the cattle tick
Boophilus microplus is reported. |
| doi_str_mv | 10.1016/0003-2697(83)90431-1 |
| format | Article |
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p-nitrophenolate ion upon hydrolysis of the pyrethroid-like compound,
trans- or
cis-p-nitrophenyl-(1
R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, at pH 7.4 where spontaneous hydrolysis is not detected. The reagent is solubilized by 0.02% Triton X-100 in the presence of 1.0% ethanol. A simple procedure for the synthesis and separation of the isomers is described. The application of the reagent to the assay of esterases which detoxify synthetic pyrethroids in the cattle tick
Boophilus microplus is reported.</description><identifier>ISSN: 0003-2697</identifier><identifier>EISSN: 1096-0309</identifier><identifier>DOI: 10.1016/0003-2697(83)90431-1</identifier><identifier>PMID: 6625152</identifier><identifier>CODEN: ANBCA2</identifier><language>eng</language><publisher>San Diego, CA: Elsevier Inc</publisher><subject>Analytical, structural and metabolic biochemistry ; Biological and medical sciences ; Chromatography, High Pressure Liquid ; Enzymes and enzyme inhibitors ; Esterases - analysis ; Fundamental and applied biological sciences. Psychology ; Hydrolases ; Isomerism ; Pyrethrins - chemical synthesis ; Pyrethrins - isolation & purification ; Ticks - enzymology</subject><ispartof>Analytical biochemistry, 1983-07, Vol.132 (1), p.105-109</ispartof><rights>1983</rights><rights>1984 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-d33ad9e877cd7419a2e338a2340158681ca2680aa2775eeb0aa0462dc95bf02a3</citedby><cites>FETCH-LOGICAL-c367t-d33ad9e877cd7419a2e338a2340158681ca2680aa2775eeb0aa0462dc95bf02a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0003-2697(83)90431-1$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27907,27908,45978</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9356880$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/6625152$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Riddles, Peter W.</creatorcontrib><creatorcontrib>Schnitzerling, Herbert J.</creatorcontrib><creatorcontrib>Davey, Patricia A.</creatorcontrib><title>Application of trans and cis isomers of p-nitrophenyl-(1 R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate to the assay of pyrethroid-hydrolyzing esterases</title><title>Analytical biochemistry</title><addtitle>Anal Biochem</addtitle><description>A continuous-rate assay for the detection of esterases which hydrolyze synthetic pyrethroids is described. The assay is based on the release of
p-nitrophenolate ion upon hydrolysis of the pyrethroid-like compound,
trans- or
cis-p-nitrophenyl-(1
R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, at pH 7.4 where spontaneous hydrolysis is not detected. The reagent is solubilized by 0.02% Triton X-100 in the presence of 1.0% ethanol. A simple procedure for the synthesis and separation of the isomers is described. The application of the reagent to the assay of esterases which detoxify synthetic pyrethroids in the cattle tick
Boophilus microplus is reported.</description><subject>Analytical, structural and metabolic biochemistry</subject><subject>Biological and medical sciences</subject><subject>Chromatography, High Pressure Liquid</subject><subject>Enzymes and enzyme inhibitors</subject><subject>Esterases - analysis</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Hydrolases</subject><subject>Isomerism</subject><subject>Pyrethrins - chemical synthesis</subject><subject>Pyrethrins - isolation & purification</subject><subject>Ticks - enzymology</subject><issn>0003-2697</issn><issn>1096-0309</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1983</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kUuLFDEUhYMoYzv6DxSyEOmGieZRlUpthGHwBQOCj3VIJ7esSLpSJunB8hf5M01PN710lZDznZPLPQg9Z_Q1o0y-oZQKwmXfrZXY9LQRjLAHaMVoLwkVtH-IVmfkMXqS809KGWtaeYEupOQta_kK_b2e5-CtKT5OOA64JDNlbCaHrc_Y57iDlA_CTCZfUpxHmJZA1gx_ufq6IYKs-RUnztsxxBTvfBU35Pi0gzIuwS42xLkazQTWpG38vQRTAJeIywjY5GyW-_wlVT5F78i4uBTD8sdPPzDkAslkyE_Ro8GEDM9O5yX6_v7dt5uP5Pbzh08317fECtkV4oQwrgfVddZ1DesNByGU4aKhrFVSMWu4VNQY3nUtwLbeaCO5s327HSg34hK9OubWmX_t6_d657OFEOr8cZ-1orLnvO0q2BxBm2LOCQY9J78zadGM6kNB-rB9fdi-VkLfF6RZtb045e-3O3Bn06mRqr886SZbE4baR23ijPWilUrRir09YlB3cech6Ww9TBacT2CLdtH_f45_jhmuIQ</recordid><startdate>19830701</startdate><enddate>19830701</enddate><creator>Riddles, Peter W.</creator><creator>Schnitzerling, Herbert J.</creator><creator>Davey, Patricia A.</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19830701</creationdate><title>Application of trans and cis isomers of p-nitrophenyl-(1 R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate to the assay of pyrethroid-hydrolyzing esterases</title><author>Riddles, Peter W. ; Schnitzerling, Herbert J. ; Davey, Patricia A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-d33ad9e877cd7419a2e338a2340158681ca2680aa2775eeb0aa0462dc95bf02a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1983</creationdate><topic>Analytical, structural and metabolic biochemistry</topic><topic>Biological and medical sciences</topic><topic>Chromatography, High Pressure Liquid</topic><topic>Enzymes and enzyme inhibitors</topic><topic>Esterases - analysis</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Hydrolases</topic><topic>Isomerism</topic><topic>Pyrethrins - chemical synthesis</topic><topic>Pyrethrins - isolation & purification</topic><topic>Ticks - enzymology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Riddles, Peter W.</creatorcontrib><creatorcontrib>Schnitzerling, Herbert J.</creatorcontrib><creatorcontrib>Davey, Patricia A.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical biochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Riddles, Peter W.</au><au>Schnitzerling, Herbert J.</au><au>Davey, Patricia A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of trans and cis isomers of p-nitrophenyl-(1 R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate to the assay of pyrethroid-hydrolyzing esterases</atitle><jtitle>Analytical biochemistry</jtitle><addtitle>Anal Biochem</addtitle><date>1983-07-01</date><risdate>1983</risdate><volume>132</volume><issue>1</issue><spage>105</spage><epage>109</epage><pages>105-109</pages><issn>0003-2697</issn><eissn>1096-0309</eissn><coden>ANBCA2</coden><abstract>A continuous-rate assay for the detection of esterases which hydrolyze synthetic pyrethroids is described. The assay is based on the release of
p-nitrophenolate ion upon hydrolysis of the pyrethroid-like compound,
trans- or
cis-p-nitrophenyl-(1
R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate, at pH 7.4 where spontaneous hydrolysis is not detected. The reagent is solubilized by 0.02% Triton X-100 in the presence of 1.0% ethanol. A simple procedure for the synthesis and separation of the isomers is described. The application of the reagent to the assay of esterases which detoxify synthetic pyrethroids in the cattle tick
Boophilus microplus is reported.</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><pmid>6625152</pmid><doi>10.1016/0003-2697(83)90431-1</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Analytical biochemistry, 1983-07, Vol.132 (1), p.105-109 |
| issn | 0003-2697 1096-0309 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_80692257 |
| source | Elsevier ScienceDirect Journals Complete - AutoHoldings; MEDLINE |
| subjects | Analytical, structural and metabolic biochemistry Biological and medical sciences Chromatography, High Pressure Liquid Enzymes and enzyme inhibitors Esterases - analysis Fundamental and applied biological sciences. Psychology Hydrolases Isomerism Pyrethrins - chemical synthesis Pyrethrins - isolation & purification Ticks - enzymology |
| title | Application of trans and cis isomers of p-nitrophenyl-(1 R,S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate to the assay of pyrethroid-hydrolyzing esterases |
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