Syntheses of four fatty acid esters of sucrose found in type B trichomes of Solanum berthaultii Hawkes (wild potato), including the major component, 6- O-decanoyl-3,4-di- O-isobutyrylsucrose

6- O-Decanoyl-3,4-di- O-isobutyrylsucrose,6- O-decanoyl-3- O-isobutyryl-4- O-[( S)-2-methylbutyryl]sucrose, 6- O-decanoyl-4- O-isobutyryl-3- O[( S)-2-methylbutyryl]sucrose, and 6- O-decanoyl-3,4-di- O-[( S)-2-methylbutyryl]sucrose have been synthesized from 3- S-allyl-3′,4′,6′-tri- O-benzyl-4,6- O-(4-methoxybenzylidene)-sucrose. 3- O-allyl-3′,4′,6′-tri- O-benzyl-4,6- O-(4-methoxybenzylidene)-sucrose.