Tetrakis(tetrahydrofuran-κO)lithium mer-tris(carbazolyl-κN)-trans-dichloro(tetrahydrofuran-κO)zirconate

In the title compound, [Li(C(4)H(8)O)(4)][ZrCl(2)(C(12)H(8)N)(3)(C(4)H(8)O)], the environment of the Zr atom is pseudo-octahedral, with the three carbazolyl ligands in a mer configuration. The counter-ion of the zirconium complex is composed of an Li atom surrounded by four tetrahydrofuran (THF) mol...

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Veröffentlicht in:	Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-02, Vol.60 (Pt 2), p.m94-m96
Hauptverfasser:	NYGREN, Cara L, BRAGG, M. E. T, TURNER, John F. C
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Crystalline state (including molecular motions in solids) Exact sciences and technology Physics Structure of solids and liquids crystallography Structure of specific crystalline solids Theory of crystal structure, crystal symmetry calculations and modeling
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	In the title compound, [Li(C(4)H(8)O)(4)][ZrCl(2)(C(12)H(8)N)(3)(C(4)H(8)O)], the environment of the Zr atom is pseudo-octahedral, with the three carbazolyl ligands in a mer configuration. The counter-ion of the zirconium complex is composed of an Li atom surrounded by four tetrahydrofuran (THF) molecules. The THF molecule attached to the Zr atom is disordered over two sites, as are two of the THF molecules in the lithium moiety. All bond distances and angles are consistent with those in complexes with similar structural entities. The Zr-N bond distances are 2.2185 (18) and 2.167 (3) A.
ISSN:	0108-2701 1600-5759
DOI:	10.1107/S0108270104000605