Remarkable Effect of a Silicon Group on the Stereoselectivity of Radical 5-exo-Trig Cyclizations

Sulfonyl radical mediated 5-exo-trig cyclization of chiral 3-silylhepta-1,6-dienes has been shown to provide cyclopentanes having up to four stereogenic centers with an unexpectedly high level of stereocontrol.

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Veröffentlicht in:	Organic letters 2004-02, Vol.6 (3), p.325-328
Hauptverfasser:	James, Philippe, Landais, Yannick
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Sprache:	eng
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container_title	Organic letters
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creator	James, Philippe Landais, Yannick
description	Sulfonyl radical mediated 5-exo-trig cyclization of chiral 3-silylhepta-1,6-dienes has been shown to provide cyclopentanes having up to four stereogenic centers with an unexpectedly high level of stereocontrol.
doi_str_mv	10.1021/ol036025v
format	Article
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title	Remarkable Effect of a Silicon Group on the Stereoselectivity of Radical 5-exo-Trig Cyclizations
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